Hydrogeochemical Characteristics and Groundwater Quality Assessment in the Asalouyeh Plain

Document Type : Original Article

Authors

1 Dept. of Earth Sciences- Faculty of Natural Sciences- University of Tabriz- Tabriz

2 Dept. of Earth Sciences, Faculty of Natural Sciences, University of Tabriz, Tabriz, Iran

Abstract

As one of Iran's pivotal industrial zones, Asalouyeh has encountered significant challenges concerning the quality of its groundwater resources in recent years. This study aims to conduct a comprehensive hydrochemical analysis and assess the groundwater quality within this plain, with particular emphasis on the impacts of industrial activities and the intrusion of saline water. To achieve this, qualitative data from eight wells and two springs were systematically collected and subjected to rigorous analysis utilizing graphical methods, including Piper and Durov diagrams, along with multivariate statistical techniques. The findings indicate that the intrusion of saline water, coupled with industrial activities, has resulted in elevated concentrations of chloride, sodium, and sulfate ions, thereby severely degrading groundwater quality, particularly in the southern and western regions of the study area. Specifically, sulfate concentrations reached up to 1711 mg/l, while sodium levels escalated to 60%, underscoring the profound influence of both natural and anthropogenic pollutants. Furthermore, the processes of reverse ion exchange and the dissolution of dolomitic and carbonate rocks were identified as predominant hydrogeochemical phenomena influencing the groundwater system. Qualitative assessments reveal that the groundwater across various sectors of the region is largely unsuitable for agricultural applications, although certain springs demonstrate relatively better quality. Additionally, the groundwater exhibits a high sedimentation potential, rendering it less suitable for industrial uses.

Keywords

Main Subjects


Ahmadi, S., Jahanshahi, R., Moeini, V., & Mali, S. (2017). Evaluation of groundwater resources in the copper mine area of Ardestan, Isfahan province. Iranian Quaternary Journal, 4(3), 387–403.
Benadela Laouni, Bekkoussa Belkacem, Gaidi Laouni. 2022. Multivariate analysis and geochemical investigations of groundwater in a semi-arid region, case of superficial aquifer in Ghriss Basin, Northwest Algeria. Journal of Groundwater Science and Engineering, 10(3): 233-249. doi: 10.19637/j.cnki.2305-7068.2022.03.003
Bouwer, H. (1978). Ground water. McGraw-Hill Inc.
Brhane, G. K. (2018). Characterization of hydrochemistry and groundwater quality evaluation for drinking purpose in Adigrat area, Tigray, northern Ethiopia. Water Science, 32(2), 213–229. https://doi.org/10.1016/j.wsj.2018.07.001.
Chidambaram, S., Karmegam, U., Prasanna, M. V., Sasidhar, P., & Vasanthavigar, M. (2011). A study on hydrochemical elucidation of coastal groundwater in and around Kalpakkam region, Southern India. Environmental Earth Sciences, 64, 1419–1431. https://doi.org/10.1007/s12665-011-0957-4.
 
 
Cortes, J. E., Muñoz, L. F., Gonzalez, C. A., Niño, J. E., Polo, A., Suspes, A., Siachoque, S. C., Hernández, A., & Trujillo, H. (2016). Hydrogeochemistry of the formation waters in the San Francisco field, UMV basin,
Colombia – A multivariate statistical approach. Journal of Hydrology, 539, 113–124. https://doi.org/10.1016/j.jhydrol.2016.05.029.
Dalton, M. G., & Upchurch, S. G. (1978). Interpretation of hydrochemical faces by factor analysis. Journal of Groundwater, 16(4), 228–233.
Fetter, C. W., Boving, T., & Kreamer, D. (2017). Contaminant hydrogeology (3rd ed.). Waveland Press.
Hadipour Hafshejani, Z., Nassery, H., & Alijani, F. (2018). The hydrogeochemical processes of Kuhdasht aquifer. Hydrogeology, 3(1), 32–46. https://doi.org/10.22034/hydro.2018.5508.
Hassanzadeh, R., Abbasnejad, A., & Hamzeh, M. A. (2011). Assessment of groundwater pollution in Kerman urban areas. Journal of Environmental Studies, 36(56), 101–110. (In Persian).  20.1001.1.10258620.1389.36.56.6.5
Hounslow, A. (1995). Water quality data: Analysis and interpretation. CRC Press.
Jabraili Andarian, N., Nadiri, A. A., & Gharekhani, M. (2024). Investigating the quantity and quality of groundwater and its effect on the hydrogeochemistry of the Azarshahr plain aquifer and identifying the possible source of contamination. Hydrogeomorphology, 11(38), 60–79. https://doi.org/10.22034/hyd.2024.58969.1710
Kalantari, N., Sajadi, Z., Makvandi, M., & Keshavarzi, M. R. (2012). Chemical properties of soil and groundwater of the Assaluyeh alluvial plain with emphasis on heavy metals contamination. Journal of Geotechnical Geology (Applied Geology), 7(4), 333–342. https://sid.ir/paper/127072/en
Karimi, S., Mohammadi, Z., & Samani, N. (2017). Evaluation of hydrochemical characteristics of groundwater and salinity evolution in Semnan Plain. Hydrogeology, 2(1), 1–19.  10.22034/hydro.2017.5237.
Khawla, K., & Mohamed, H. (2020). Hydrogeochemical assessment of groundwater quality in greenhouse intensive agricultural areas in coastal zone of Tunisia: Case of Teboulba region. Groundwater for Sustainable Development, 10, 100335. https://doi.org/10.1016/j.gsd.2020.100335.
Koundouri, P., & Groom, B. (2009). Groundwater management: An overview of hydro-geology, economic values, and principles of management. Groundwater-Volume III, 101.
Kubicz, J., Lochyński, P., Pawełczyk, A., & Karczewski, M. (2021). Effects of drought on environmental health risk posed by groundwater contamination. Chemosphere, 263, 128145. https://doi.org/10.1016/j.chemosphere.2020.128145.
Lakshmanan, E., Kannan, R., & Senthil Kumar, M. (2003). Major ion chemistry and identification of hydrogeochemical processes of groundwater in a part of Kancheepuram district, Tamil Nadu, India. Environmental Geosciences, 10(4), 157–166. https://doi.org/10.1306/eg.0820303011.
Monjerezi, M., Vogt, R. D., Aagaard, P., & Saka, J. D. (2012). The hydro-geochemistry of groundwater resources in an area with prevailing saline groundwater, lower Shire Valley, Malawi. Journal of African Earth Sciences, 68, 67–81. https://doi.org/10.1016/j.jafrearsci.2012.07.002
Nadiri, A., Navin, F., Barzegari, A., Ojaghi, M., & Nouri, N. (2022). Investigating the hydrochemistry and quality of water resources in the Hajilarchai basin and determining the origin of trace elements. Hydrogeomorphology, 8(29), 127–148.  https://doi.org/10.22034/hyd.2022.48533.1609.
Piper, A. M. (1944). A graphical procedure in the geochemical interpretation of water analyses. American Geophysical Union, 25, 914–923.
Ravindra, K., Thind, P. S., Mor, S., Singh, T., & Mor, S. (2019). Evaluation of groundwater contamination in Chandigarh: Source identification and health risk assessment. Environmental Pollution, 255, 113062. https://doi.org/10.1016/j.envpol.2019.113062.
Redwan, M., & Moneim, A. A. A. (2016). Factors controlling groundwater hydrogeochemistry in the area west of Tahta, Sohag, Upper Egypt. Journal of African Earth Sciences, 118, 328–338. https://doi.org/10.1016/j.jafrearsci.2015.10.002.
Şener, Ş., Şener, E., & Davraz, A. (2017). Evaluation of water quality using water quality index (WQI) method and GIS in Aksu River (SW-Turkey). Science of the Total Environment, 584, 131–144. https://doi.org/10.1016/j.scitotenv.2017.01.102.
Shrestha, S., Bach, T. V., & Pandey, V. P. (2016). Climate change impacts on groundwater resources in Mekong Delta under representative concentration pathways (RCPs) scenarios. Environmental Science & Policy, 61, 1–13. https://doi.org/10.1016/j.envsci.2016.03.001.
Singhal, B. B. S., & Gupta, R. P. (1999). Applied hydrogeology of fractured rocks. Kluwer Academic Publishers.